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Title

Guidance for the WDOE NWTPH-Dx Method for Testing Groundwater: Silica Gel Cleanup Protocol Revision

 
Publication number Date Published Date Revised
24-03-001February 2024April 2024
VIEW NOW Guidance for the WDOE NWTPH-Dx Method for Testing Groundwater: Silica Gel Cleanup Protocol Revision (Number of pages: 49) (Publication Size: 1354KB)




Appendix B. Analytical QC Tables
(16 pages) (865KB)

Appendix C. Data Validation Report
(12 pages) (637KB)

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Author(s) Hobbs, W., K. Bailey, J. Protasio, and C. Frans
Description In 1997, the Washington State Department of Ecology (Ecology) published analytical methods for analyzing total petroleum hydrocarbons (TPH) (NWTPH; Ecology 1997). Under guidance by Ecology’s Toxic Cleanup Program (TCP), a silica gel cleanup (SGC) step can be employed where groundwater may contain a component of naturally occurring polar compounds that may interfere with the NWTPH analysis for diesel range organics (DRO). The goal of this project was to provide an updated protocol on how laboratories use silica gel cleanup (SGC) on groundwater samples contaminated with weathered DRO.

Twenty-three regional labs accredited by Ecology for the NWTPH method were surveyed to determine what SGC protocols are being used. Thirteen labs responded, and current protocols varied across labs. Manchester Environmental Laboratory (MEL) wrote and tested a revised SGC protocol based on published silica gel column approaches and EPA Method 3630. The revised protocol also incorporated a reverse surrogate of decanoic acid to evaluate the efficacy of removing polar compounds.

Seven of the 13 contract labs agreed to participate in a paid inter-laboratory comparison study with MEL to evaluate the revised protocol. The results of the inter-lab study showed that the revised SGC protocol is repeatable and reproducible among the labs. TCP should begin disseminating the revised protocol internally to site managers and consider revising the NWTPH method guidance.
NOTES Erratum for revised version (April 2024): Table 2 updated to include Friedman & Bruya, Inc.'s silica gel cleanup method information.
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Contact William Hobbs at 564-669-3028 or william.hobbs@ecy.wa.gov
Keywords polar metabolite, hydrocarbon, NWTPH, NWTPH-Dx analytical method, Silica Gel Cleanup (SGC), Diesel-range organics, Silica Gel
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